Vertically Aligned Carbon Nanotubes Research Articles

Adhesion characteristics of carbon nanotube gecko tapes for micrometer-sized particles

ABSTRACT A detailed understanding of the adhesive properties of a carbon nanotube (CNT)-based gecko tape with respect to microscale particles is necessary for its practical application as a supporting medium for specific solid materials. We obtained the force curves of vertically aligned CNTs (VACNTs) for individual microparticles of various diameters using atomic force microscopy and evaluated their adhesion force and adhesion length. The measured adhesive force followed the apparent contact area with increasing embedding depth and was size-dependent at scales of several tens of micrometers. The adhesive forces measured for a 20 µm-diameter bead was significantly higher than those for larger particles, which may be related to inclination of the adherent surface against the VACNT tape surface. The adhesion length depended on the type of the CNTs comprising the VACNT, rather than on the bead size. The evaluation of VACNTs with different morphologies suggested that the flexibility of the individual CNTs and the density of the CNT – CNT interconnections in the VACNTs were important factors for obtaining the true contact area to realize better adhesion of micrometer-sized particles.

Effects of CCVD parameters on the growth of VACNT over AZO substrate

Both, aluminum doped zinc oxide (AZO) and vertically aligned carbon nanotubes (VACNT) have outstanding properties and promising applications in the future, however, there is little information in the scientific literature on whether this is feasible. In this study, we investigated the effects of catalyst layer deposition parameters and the synthesis parameters by using a simple and cost-effective dip coating method to form alumina support layer and iron and cobalt bimetal catalyst layer on the AZO surface thereafter performing synthesis via catalytic chemical vapor deposition technique at 650 °C.In order to gain useful information about the structure of the VACNTs, several parameters were varied during both catalyst layer preparation (e.g. catalyst ink concentration) and CCVD synthesis (e.g. water vapor gas feed, the presence of hydrogen gas). The resulting samples were investigated by scanning electron microscopy, transmission electron microscopy and Raman spectroscopy. The results indicated that the length and structure of CNTs were strongly affected by the catalyst ink concentration and water vapor.

Impact of electrical aging on x-ray image quality and dose rate with vertically aligned carbon nanotube based cold cathode electron beam (C-beam)

The adoption of vertically aligned carbon nanotubes (VACNTs) as electron emitters in x-ray generation has opened a new path for medical imaging technology advancement. With their outstanding electron emission capabilities, VACNTs provide a distinct advantage in miniaturizing and improving the performance of x-ray devices. This research focuses on the effect of electrical aging on x-ray imaging quality and the dose rate while using VACNTs as the electron source. The study includes a thorough examination of the electrical aging effects on VACNT-based x-ray systems, with an emphasis on changes in emission characteristics, beam stability, and the resulting variations in x-ray output. Experiment results show that electrical aging has a considerable impact on the performance of VACNT-based x-ray sources, with visible changes in electron emission parameters and subsequent consequences on x-ray imaging quality. Furthermore, the study investigates the relationship between electrical aging and the x-ray dose rate, providing vital insights into radiation exposure optimization in medical diagnostics.

Interplay of the forces governing steroid hormone micropollutant adsorption in vertically-aligned carbon nanotube membrane nanopores

Vertically-aligned carbon nanotube (VaCNT) membranes allow water to conduct rapidly at low pressures and open up the possibility for water purification and desalination, although the ultralow viscous stress in hydrophobic and low-tortuosity nanopores prevents surface interactions with contaminants. In this experimental investigation, steroid hormone micropollutant adsorption by VaCNT membranes is quantified and explained via the interplay of the hydrodynamic drag and friction forces acting on the hormone, and the adhesive and repulsive forces between the hormone and the inner carbon nanotube wall. It is concluded that a drag force above 2.2 × 10−3 pN overcomes the friction force resulting in insignificant adsorption, whereas lowering the drag force from 2.2 × 10−3 to 4.3 × 10−4 pN increases the adsorbed mass of hormones from zero to 0.4 ng cm−2. At a low drag force of 1.6 × 10−3 pN, the adsorbed mass of four hormones is correlated with the hormone−wall adhesive (van der Waals) force. These findings explain micropollutant adsorption in nanopores via the forces acting on the micropollutant along and perpendicular to the flow, which can be exploited for selectivity.

The Synthesis of Sponge-like V2O5/CNT Hybrid Nanostructures Using Vertically Aligned CNTs as Templates.

The fabrication of sponge-like vanadium pentoxide (V2O5) nanostructures using vertically aligned carbon nanotubes (VACNTs) as a template is presented. The VACNTs were grown on silicon substrates by chemical vapor deposition using the Fe/Al bilayer catalyst approach. The V2O5 nanostructures were obtained from the thermal oxidation of metallic vanadium deposited on the VACNTs. Different oxidation temperatures and vanadium thicknesses were used to study the influence of these parameters on the stability of the carbon template and the formation of the V2O5 nanostructures. The morphology of the samples was analyzed by scanning electron microscopy, and the structural characterization was performed by Raman, energy-dispersive X-ray, and X-ray photoelectron spectroscopies. Due to the catalytic properties of V2O5 in the decomposition of carbonaceous materials, it was possible to obtain supported sponge-like structures based on V2O5/CNT composites, in which the CNTs exhibit an increase in their graphitization. The VACNTs can be removed or preserved by modulating the thermal oxidation process and the vanadium thickness.

Evaluation of vertical alignment in carbon nanotubes: A quantitative approach

An automated quantitative study of the alignment of vertically aligned carbon nanotubes (VA-CNTs) from scanning electron microscopy (SEM) images has been demonstrated. It is based on the fact that the image gradient (directional change in intensity or color) at every pixel in the image contains the information about the anisotropy at that particular pixel i.e., the local alignment is maintained in the orthogonal direction to the gradient. Structure tensor metrics are formulated demonstrating to be able to summarize the distribution of gradient directions within the neighborhood of any pixel within a two-dimensional domain (surface). An image analysis is presented that evaluates the alignment in desired regions of interest (ROIs) in SEM images of VA-CNTs. This method has been exploited to study the alignment of two different kinds of VA-CNTs: one grown via the thermal chemical vapor deposition (T-CVD) method and the second synthesized via the plasma enhanced chemical vapor deposition (PE-CVD) method.

Searching for Dark Matter with vertically-aligned carbon nanotubes:The ANDROMeDa project

The ANDROMeDa project, recently funded by the Italian ministry of research with a 1M€ grant, aims to develop a novel light dark matter (DM) detector sensitive to DM-electron recoil in a target of vertically-aligned carbon nanotubes: the “dark-PMT”. Thanks to their vanishing density in the direction of the tube axis, carbon nanotubes allow a scattered electron to leave the target without being re-absorbed only if it travels parallel to the tubes. Therefore the detector is expected to have directional sensitivity, a key feature in DM searches. With only 1 g of exposure per year and a careful suppression of the backgrounds, such detector might achieve world-leading sensitivity for DM masses below 30 MeV.

Boosting the Performance of on-Chip Vertically-Aligned Carbon Nanotube Supercapacitors Via Solvent-Free Radiofrequency Nitrogen Plasma Treatment

Supercapacitors are essential components for energy storage devices in many fields, including renewable energy systems, electric vehicles, and portable electronics [1]. Carbon nanotube arrays have shown great promise for use in supercapacitors due to their high surface area and excellent electrical conductivity. However, the specific capacitance of these arrays needs to be increased to improve the overall energy storage capacitance of the supercapacitor.This study presents an innovative approach to enhance the specific capacitance of on-chip vertically-aligned carbon nanotube (VACNT) structures for the development of high-performance supercapacitors. The proposed technique involves employing a solvent-free radiofrequency (RF) nitrogen plasma treatment to dope nitrogen onto VACNT surfaces. The plasma doping process utilizes reactive ion etching-induced coupled plasma (RIE-ICP) to optimize the parameters for nitrogen incorporation [2]. The nitrogen plasma treatment introduces nitrogen-containing functional groups, thereby improving their specific capacitance. The dry process is compatible with semiconductor fabrication and can be integrated into existing manufacturing techniques [1]. This study provides a promising avenue for tailoring the nitrogen doping process to achieve desired performance enhancements for on-chip VACNT supercapacitors.The plasma doping process involves the generation of reactive nitrogen species in the plasma, which subsequently interact with the VACNT surfaces. Under the influence of the RF electric field, nitrogen gas molecules are ionized and can react with the carbon atoms of the VACNTs, resulting in the formation of nitrogen-containing functional groups and the substitution of carbon atoms with nitrogen atoms within the carbon lattice [3].The improved capacitance can be attributed to the incorporation of nitrogen functional groups and to the modification of the electronic properties of the carbon nanotubes, including additional charge carriers, leading to an increase in electrical conductivity [4] and introduction of the pseudocapacitance effect [5]. There are various types of nitrogen species in the carbon lattice, such as pyridinic, pyrrolic, and graphitic nitrogen. Among these, pyridinic and pyrrolic nitrogen are known to be more electrochemically active [5], contributing to the enhanced specific capacitance. The increased electrical conductivity stems from the introduction of nitrogen dopants, which alter the electronic structure of the VACNTs, creating localized states near the Fermi level and thus facilitating charge transport [4].The level of nitrogen doping depends on several process factors, including the plasma power, gas pressure, and treatment duration. Higher plasma power generates a larger number of reactive nitrogen, while lower gas pressure results in a higher ionization efficiency. Furthermore, a longer treatment duration increases the chance of nitrogen incorporation into the VACNT structures [3]. By carefully controlling these parameters during the nitrogen plasma treatment, it is possible to tailor the nitrogen doping process to achieve the desired performance enhancement for on-chip VACNT supercapacitors.The treatment is performed in a chamber with a pressure of 10 Pa, a nitrogen gas flow rate of 10 sccm, an ICP power of 200W, and a bias voltage of -120 V. We report a specific capacitance of modified VACNTs of 18 mF/cm2(Figure 1), nearly twice that of pristine samples (Figure1(B)), for dense arrays of 1012 CNTs/ cm2. XPS result confirms 11.76% nitrogen content and 13% oxygen content in treated samples (N-VACNTs), aligning with previous studies on wet process nitrogen-doped carbon nanotubes [5]. Oxygen content also plays a crucial role in VACNT-based supercapacitor performance, improving surface wettability which will reduce the resistance between electrode and electrolyte [6, 7]. However, excessive oxygen content can negatively affect VACNT supercapacitor lifetime. By finding the trade-off between nitrogen and oxygen content, we optimized the doping process, enhancing specific capacitance, stability (Figure 2), and lifetime for on-chip VACNT structures.In conclusion, our study demonstrates that the solvent-free RF nitrogen plasma treatment can effectively enhance the specific capacitance of on-chip VACNT structures by up to 100%, making them suitable for integration into high-performance on-chip supercapacitor.

Micro-DRIFTS for small area hyper-black spectroscopy.

We have developed a low-cost micro-diffuse reflectance infrared Fourier transform spectroscopic (micro-DRIFTS) setup for measuring the reflectance of small area diffuse samples. The system performance is characterized and then demonstrated on small area vertically aligned carbon nanotube (VACNT) samples. We find that our system can measure samples with a spatial resolution of approximately 140 µm with sensitivities of 10s of ppm in the 2 µm - 18 µm spectral window. Our uncertainty budget is presented along with how our measured reflectance can be equated to directional-hemispherical reflectance.

Carbon nanotube microbeads for enhanced gas heating in a fluidized bed solar air collector

A novel approach utilizing vertically-aligned carbon nanotube (VACNT) as solar heat absorbers is proposed for efficient gas heating in a concentrated fluidized bed solar air collector (FBSAC). The VACNT powder was fabricated into CNT beads suitable for fluidized bed applications through macronization and densification. The CNT bead showed an increase in size and a 6.8 times increase in apparent density. The increase in sphericity and a significant decrease in the repose angle indicated improved particle fluidity. The prepared CNT beads demonstrated an absorptivity similar to VACNT, along with increased thermal conductivity and specific heat capacity, indicating superior thermophysical properties compared to conventional CNTs. Moreover, the reduced electrostatic charge generation minimizes the issue of particle attachment on the transmission window. The heat absorption characteristics of air in FBSAC (50 mm i.d. × 150 mm height) with CNT microbeads were determined. The FBSAC achieved a maximum gas temperature of approximately 150 °C. The CNT bead achieved a higher temperature difference of the gas per irradiance and a more comprehensive operating range of gas velocities up to 0.16 m/s than VACNT. The FBSAC with CNT beads exhibited a maximum thermal efficiency of 30.3 % and higher efficiency of 8–21 % than CNT powders at gas velocity of 0.11 m/s. A correlation was proposed to predict the thermal efficiencies of the FBSACs with different particles from dimensionless numbers considering particles dynamics and thermophysical properties.

Phonon Thermal Transport at Interfaces of a Graphene/Vertically Aligned Carbon Nanotubes/Hexagonal Boron Nitride Sandwiched Heterostructure

Molecular dynamics simulation is used to calculate the interfacial thermal resistance of a graphene/carbon nanotubes/hexagonal boron nitride (Gr/CNTs/hBN) sandwiched heterostructure, in which vertically aligned carbon nanotube (VACNT) arrays are covalently bonded to graphene and hexagonal boron nitride layers. We find that the interfacial thermal resistance (ITR) of the Gr/VACNT/hBN sandwiched heterostructure is one to two orders of magnitude smaller than the ITR of a Gr/hBN van der Waals heterostructure with the same plane size. It is observed that covalent bonding effectively enhances the phonon coupling between Gr and hBN layers, resulting in an increase in the overlap factor of phonon density of states between Gr and hBN, thus reducing the ITR of Gr and hBN. In addition, the chirality, size (diameter and length), and packing density of sandwich-layer VACNTs have an important influence on the ITR of the heterostructure. Under the same CNT diameter and length, the ITR of the sandwiched heterostructure with armchair-shaped VACNTs is higher than that of the sandwiched heterostructure with zigzag-shaped VACNTs due to the different chemical bonding of chiral CNTs with Gr and hBN. When the armchair-shaped CNT diameter increases or the length decreases, the ITR of the sandwiched heterostructure tends to decrease. Moreover, the increase in the VACNT packing density also leads to a continuous decrease in the ITR of the sandwiched heterostructure, attributed to the extremely high intrinsic thermal conductivity of CNTs and the increase of out-of-plane heat transfer channels. This work may be helpful for understanding the mechanism for ITR in multilayer vertical heterostructures, and provides theoretical guidance for a new strategy to regulate the interlayer thermal resistance of heterostructures by optimizing the design of sandwich layer thermal interface materials.

Integration of vertically-aligned carbon nanotubes with superconducting nanowire single photon detectors

We report on initial fabrication efforts in the integration of superconducting nanowire single-photon detectors (SNSPDs) with vertically aligned carbon nanotubes (VACNTs) with the goal of creating a wideband single-photon detector. SNSPDs provide high detection efficiencies and low dark count rates, while the VACNTs are excellent broadband optical absorbers. Combining these technologies could potentially enable the development of highly sensitive and versatile optical sensors for a variety of applications, such as spectroscopy, optical communication, and imaging in light starved environments. We developed two fabrication processes for the integration of VACNTs on SNSPDs. The first involves capping the SNSPDs with a protective layer and growing the VACNTs directly above nanowires. Thermal and electrical characterizations of the devices demonstrated a degradation of the superconducting qualities of the SNSPDs. The second process involved suspending the SNSPDs on a thin membrane via a backside etch, where VACNTs were then grown on the backside of the membranes below the nanowires. The membrane style devices showed no degradation in the superconducting properties of the nanowires. Measurements of the membrane style devices before and after the VACNT growth display similar superconducting properties and photon count rates.

Engineered vertically-aligned carbon nanotube microarray for self-concentrated SERS detection

Surface-enhanced Raman spectroscopy (SERS) is a high-sensitivity, label-free detection method that shows promise for various analytical applications. Hydrophobic low-adhesion surfaces make excellent SERS substrates since they allow the usage of trace analytes at low concentrations by efficiently enriching them into the SERS-active region. Herein, we introduce a hydrophobic surface-enhanced Raman scattering substrate based on engineered carbon nanotube arrays (CNT-SERS) and study the role of structural design in both micro- and nanoscales. This substrate has predetermined microstructures with a high aspect ratio, providing controlled self-enrichment capability. Likewise, the vertically aligned 3D surface porosity enables enhanced sensitivity, exhibiting an amplification in the SERS signal of ∼507.6%. The applicability of CNT-SERS to environmental science is shown by analyzing 5 nM of industrial dye (crystal violet) with 121 consecutive SERS measurements that exhibit distinct peaks from the molecules. We explore the underlying mechanics governing the enrichment behavior during analyte deposition on microarrays and discuss the effective strategies for designing hydrophobic SERS substrates. A theoretical model predicting the extent of concentration is developed and compared with the experimental results. In addition, we suggest a robust analyte concentration strategy inspired by plants in the Bromeliaceae family. The proposed method utilizes a hydrophobic yet flexible CNT SERS substrate that prevents roll-off failures during droplet loading.

Superior thermal transport properties of vertically aligned carbon nanotubes tailored through mesoscale architectures

Thermal transport properties play a critical role in the performance of lightweight foams used as shock-absorbing layers in helmets, sports gear, and electronic packaging. We report superior tailored thermal properties achieved at lightweight in vertically aligned carbon nanotube (VACNT) foams by introducing mesoscale hexagonally close-packed cylindrical architecture. We measure thermal diffusivity (α) using a laser flash technique and specific heat capacity (Cp) by differential scanning calorimetry at varying temperatures from 25 °C to 200 °C from which we determine the thermal conductivity and the thermal resistance as functions of temperature. The architected VACNTs exhibit similar α and Cp as non-architected VACNTs but exhibit higher intrinsic thermal conductivity (ki) and lower intrinsic thermal resistance (Ri) compared to the non-architected VACNTs. This improvement in ki and Ri arises due to the higher intrinsic density of VACNTs achieved by exploiting a synthesis size effect—the geometrically confined CVD synthesis which leads to higher vertical alignment and number density of CNTs. The effective thermal conductivity keff of VACNT foams follows a desirable sub-linear scaling with the density—which is tailored by the architecture—in contrast to the higher order scaling observed in other materials. The superior thermal transport properties of architected VACNTs enable lightweight protective materials for extreme engineering applications.

Thermal boundary resistance and thermal rectification in VACNT arrays integrated with SnZn alloys

Thermal rectification (TR) phenomena in carbon nanotubes (CNTs) have been previously foreseen through theoretical predictions; however, its experimental realization in bulk CNT arrays remains relatively unexplored. Herein, we have synthesized vertically aligned carbon nanotube (VACNT) arrays of ∼ 4.5 mm in length on a 4-inch silicon wafer by a combined bubble-assisted chemical vapor deposition method. By integrating these VACNT arrays with SnZn alloys, we have successfully developed devices capable of functioning across a wide temperature range spanning from 200 °C to 400 °C. Notably, the thermal boundary resistances (TBR) between the VACNTs and SnZn alloy exhibit pronounced dependence on the alloy's composition, exhibiting variations ranging from 0.12 cm2KW−1 to 1.12 cm2KW−1. Of particular significance, the TBRs of Sn50Zn50/VACNT compounds in the forward direction were found to fall within the range of 0.63–0.98 cm2KW−1 in the temperature range from120 °C to 180 °C, while in the backward direction, they exhibited values in the range of 0.13–0.34 cm2KW−1. These contrasting TBR values highlight a marked thermal rectification performance with a substantial TR coefficient between 0.49 and 0.66. Our comprehensive investigation sheds valuable insights into the TR effects within VACNTs and metal/alloy interfaces, presenting a promising avenue for the development of future thermal logic circuits and thermal transistors.

Composite laminates reinforced by vertically aligned carbon nanotubes: Detailed manufacturing process, from nanotubes transfer to composite consolidation

Nano-constituent incorporation into composites has been extensively studied in the literature due to its improvement in static and dynamic mechanical properties, as well as its prevention from interlaminar crack initiation and propagation. This work introduces a detailed manufacturing process of nano-engineered composite laminates, from impregnation to consolidation, without damaging the initial morphology of carbon nanotubes transferred on prepreg interfaces. Based on prepreg and vertically aligned carbon nanotubes (VACNTs) synthesized on an aluminium alloy (Al) substrate, the impregnation step allows for the transfer of VACNTs onto the prepreg surface through partial resin-rising capillarity. The Al alloy substrate is then removed from the VACNTs through a separation step, ensuring highly effective and repeatable transfer with more than 80% VACNTs transferred onto the prepreg surface. This paper provides insight into the impregnation and transfer processes and guides the choice of process parameters to ensure minimal VACNTs buckling during the consolidation of the hybrid composites at high pressure in an autoclave.

Optimizing the growth of vertically aligned carbon nanotubes by literature mining and high-throughput experiments

Vertically aligned carbon nanotube (VACNT) arrays with good mechanical properties and high thermal conductivity can be used as effective thermal interface materials in thermal management. In order to take advantage of the high thermal conductivity along the axis of nanotubes, the quality and height of the arrays need to be optimized. However, the immense synthesis parameter space for VACNT arrays and the interdependence of structural features make it challenging to improve both their height and quality. We have developed a literature mining approach combined with machine learning and high-throughput design to efficiently optimize the height and quality of the arrays. To reveal the underlying relationship between VACNT structures and their key growth parameters, we used random forest regression (RFR) and SHapley Additive exPlanation (SHAP) methods to model a set of published sample data (864 samples). High-throughput experiments were designed to change 4 key parameters: growth temperature, growth time, catalyst composition, and concentration of the carbon source. It was found that a screened Fe/Gd/Al2O3 catalyst was able to grow VACNT arrays with millimeter-scale height and improved quality. Our results demonstrate that this approach can effectively deal with multi-parameter processes such as nanotube growth and improve control over their structures.

Towards 3D Lithium-Ion Full Cells Using Honeycomb-Patterned Carbon Nanotube Forests

The growing demand for electric vehicles and portable electronics has created a significant interest in the scalability, recyclability, and economics of both traditional and emerging battery technologies. Although lithium-ion batteries (LiB) are approaching their theoretical energy density, they will remain a widespread and promising technology as alternative (e.g., Li-metal) chemistries and solid-state architectures are still in relatively early stages of commercial scale-up. Yet, LiB performance can be improved by redesigning the cell geometry to move from planar to 3D designs. 3D designs enable the use of thick electrodes to increase the cell level energy density by minimizing the volume and mass contributions of inactive components, such as current collectors or separators. The rationale for 3D full cell designs lies in the relationship between electrode geometry and the respective energy and power densities. When compared to a planar design, 3D architectures allow for a higher surface area for the same volume and footprint of cell. As a result, a given volume of active material can be distributed with a lower electrode feature thickness. Compared to a planar electrode of a given energy density, the lower thickness contributes to a quadratic improvement in power density which decouples the inherent tradeoff between the energy density and power density that is experienced by planar cells. This suggests that a high aspect ratio 3D cell would give greater power per footprint area while retaining high areal energy density. To meet these criteria, the materials used in fabricating 3D cells must be processable in a manner enabling precise control over geometry, layer conformality and porosity.We are developing thick 3D “honeycomb” full cells by starting with patterned, vertically aligned carbon nanotubes (VA-CNTs) as current collectors. CNTs are widely known to have high thermal and electrical conductivities, and to be mechanically durable; properties which make them an ideal scaffold for 3D cell development. VA-CNTs (“forests”) form by self-organization of CNTs during chemical vapor deposition (CVD) on substrates using common hydrocarbon sources (e.g., C2H2, C2H4). However, well-established CNT growth techniques utilize rigid non-conductive substrates, such as silicon wafers, which necessitates a transfer to a suitable substrate for electrochemical applications. Recently, we translated insights from CNT growth on silicon wafer substrates to grow CNT forests on thin metal foils (Cu) suitable for electrode fabrication. We did this by optimizing the moisture level within the CVD furnace, and using a thin-film stack that forms high-density nanoparticles upon annealing while preventing the poisoning of the Fe catalyst by diffusion of Cu. The resulting CNT forests can reach thicknesses over 350 μm and can be grown from patterned catalyst films having regular hole arrays with feature sizes as small as ~5 μm.Thick composite electrodes are then created by coating CNT forests with Si thin films by CVD. The inherent nanoporosity of the CNT forests (>95%) allows for precursor diffusion into the entirety of the forest cross-section and conformal coating of the individual CNTs. The CVD process is tuned to create dense electrodes with tailored Si loading that can range from ~10 to ~90 at.%. Half-cells using monolithic and honeycomb patterned Si-CNT electrodes (~250 μm tall), Li-metal foil, and a liquid electrolyte/separator combination have been cycled over a range of current densities, demonstrating the electronic connection between the deposited Si and Cu foil via the aligned CNTs. At low current densities and high Si loadings these honeycomb electrodes can exhibit large gravimetric (~1500 mAh/gSi) and areal (~12 mAh/cm2) capacities, with honeycomb Si-CNT composites exhibiting reduced capacity fading when compared to non-patterned electrodes.We continue by investigating these Si-CNT composites as a template for a 3D full cell design. In literature, the difficulty of producing 3D full cells comes from the need to produce high conformality electrolyte films that are pinhole free and which demonstrate sufficient ionic conductivity. To address this issue, we utilize an initiated chemical vapor deposition (iCVD) process to deposit conformal poly(hydroxyethyl methacrylate-co-ethylene glycol diacrylate) thin films on the high aspect ratio CNT forests. These copolymer films are doped with lithium salts to exhibit ionic conductivities on the order of ~10-6 to 10-5 S/cm, which is among the highest conductivities ever exhibited by conformal electrolyte technologies. To complete a full cell design, a slurry-based cathode will be infiltrated into the iCVD coated Si-CNT composite electrodes, from which we aim to assess the cycling behavior and compare the areal energy and power densities of non-patterned and honeycomb architectures.

Phase and orientation effects in X-ray attenuation of carbonaceous epoxy composites

Composites made of carbon nanotubes (CNTs) reinforced in an epoxy matrix have already been successfully used as electromagnetic interference shielding materials. Different weight fractions of randomly distributed and vertically aligned multiwall carbon nanotubes (MWCNTs), graphite, and carbon fiber reinforced in the epoxy matrix were used to make these composites. The comparisons of percentage attenuation of different composite materials were studied under both diagnostic or hard (narrow beam geometry) and soft X-rays (monochromatic X-rays beam). It was found that the concentration of CNTs and graphite in epoxy composites affects attenuation. The results also demonstrate that the percentage attenuation for CNTs (as made) epoxy composite is always higher than graphite epoxy and treated CNTs epoxy composite at any concentration at the same thickness and tube voltage. This study also confirmed that the metal catalyst particles present in CNTs contribute to a considerable attenuation of X-rays along with CNTs and also demonstrated that the increase in metal content inside CNTs increases the attenuation. For hard X-rays, the orientation of CNTs in composites affects attenuation, and this effect gradually weakens at higher tube voltages. Vertically aligned carbon nanotubes (VACNT) array epoxy, and the thin composites are not suitable to attenuate diagnostic X-rays coming from high tube potential. For thin samples, VACNT array epoxy composites always perform better on attenuation of soft X-rays than randomly oriented CNTs in composites with any other composition lower than 15 wt %. This study also showed that there is a difference in the attenuation of soft X-rays amongst CNTs, graphite, and carbon fiber epoxy composites, which confirms that the attenuation depends on the geometry of the carbon structures. There is a clear effect of the orientation of CNTs in VACNTs epoxy composite on soft X-ray attenuation, and it shows that the radial direction of CNTs attenuates more X-ray radiation than the tube axis direction.

Performance evaluation of VACNT arrays under simulated LEO plasma environment

The space applications of vertical aligned carbon nanotube (VACNT) arrays have attracted many researchers' interest in recent years. However, the influences of various space environmental factors on the VACNT arrays are mostly unknown. In this paper, the ground-based experiments of simulated plasma environment in low earth orbit (LEO) were presented. VACNT arrays synthesized by chemical vapor deposition are exposed in the vacuum chamber under different plasma parameters (time, plasma temperature, and plasma density). The morphological, structural as well as chemical surface modifications were investigated by scanning electron microscopy, Raman spectroscopy, transmission electron microscopy and x-ray photoelectron spectroscopy. Correlations of the plasma parameters to the adhesion of VACNT arrays were analyzed at micro-scale and nano-scale by nanoindentation and atomic force microscopy. The obtained data confirm that exposure to simulated LEO plasma environment will lead to the increase of defect degree, the damage of tube walls between CNTs, which will weaken the adhesion of VACNT arrays. However, the plasma will also react with the carbon tubes on the surface and introduce many polar groups, thus consolidating the adhesion of VACNT arrays. Our results provide experimental predictions needed to guide the design of VACNT arrays for space applications.